94. Plutonium

Name: Plutonium
Symbol: Pu
Atomic Number: 94
Atomic Mass: (244.0) amu
Melting Point: 639.5 °C (912.65 °K, 1183.1 °F)
Boiling Point: 3235.0 °C (3508.15 °K, 5855.0 °F)
Number of Protons/Electrons: 94
Number of Neutrons: 150
Classification: Rare Earth
Crystal Structure: Monoclinic
Density(293 K): 19.84 g/cm3
Color: Unknown

Plutonium was the second transuranium element of the actinide series to be discovered. By far of greatest importance is the isotope 239Pu, which has a half-life of more than 20000 years. One kilogram is equivalent to about 22 million kilowatt hours of heat energy. The complete detonation of a kilogram of plutonium produces an explosion equal to about 20000 tons of chemical explosive. The various nuclear applications of plutonium are well known. The isotope 233Pu was used in the American Apollo lunar missions to power seismic and other equipment on the lunar surface. Plutonium contamination is an emotive environmental problem.

Plutonium was discovered in 1940 by Dr. Glenn T. Seaborg, Edwin M. McMillan, J. W. Kennedy, and A. C. Wahl by deuteron bombardment of uranium in the 60-inch cyclotron of the Berkeley Radiation Laboratory at the University of California, Berkeley, but the discovery was kept secret. It was named after the planet Pluto, having been discovered directly after neptunium (which itself was one higher on the periodic table than uranium), by analogy with the ordering of the planets in the solar system. During the Manhattan Project, large reactors were set up in Hanford, Washington for the production of plutonium, which was used in two of the first atomic bombs (the first was tested at Trinity site, the second dropped on Nagasaki, Japan).

All isotopes and compounds of plutonium are toxic and radioactive. While plutonium is sometimes described in media reports as "the most toxic substance known to man", there is general agreement among experts in the field that this is incorrect. As of 2003, there has yet to be a single human death officially attributed to plutonium exposure. Naturally-occurring radium is about 200 times more radiotoxic than plutonium, and some organic toxins like botulism toxin are still more toxic. Botulism toxin, in particular, has a lethal dose in the hundreds of pg per kg, far less than the quantity of plutonium that poses a significant cancer risk. In addition, beta and gamma emitters (including the C-14 and K-40 in nearly all food) can cause cancer on casual contact, which alpha emitters cannot.

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